NIR electrochemiluminescence from Au25− nanoclusters facilitated by highly oxidizing and reducing co-reactant radicals
Author:
Affiliation:
1. Department of Chemistry and Centre for Advanced Materials and Biomaterials Research
2. The University of Western Ontario
3. London, Canada
Abstract
By means of spooling spectroscopy, we demonstrate our discovery on near-infrared electrochemiluminescence of Au25− nanoclusters at 950 and 900 nm, which can be attributed to the Au25−*, Au250* and Au25+* excited species being controllable chemically and electrochemically.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC01086H
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