Kinetics of CN (<i>v</i> = 1) reactions with butadiene isomers at low temperature by cw-cavity ring-down in a pulsed Laval flow with theoretical modelling of rates and entrance channel branching-Reference-Cited by-同舟云学术

Kinetics of CN (v = 1) reactions with butadiene isomers at low temperature by cw-cavity ring-down in a pulsed Laval flow with theoretical modelling of rates and entrance channel branching

Published:2023 Issue: Volume:245 Page:245-260
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Thawoos Shameemah¹,Hall Gregory E.²^ORCID,Cavallotti Carlo³,Suits Arthur G.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Missouri, Columbia, MO 65211, USA

2. Chemistry Division, Brookhaven National Laboratory, Upton, NY 11973, USA

3. Department of Chemistry, Materials, and Chemical Engineering “G. Natta”, Politecnico di Milano, Milano 20133, Italy

Abstract

Continuous-wave-cavity ring-down spectroscopy (CRDS) coupled with a pulsed uniform supersonic flow (Laval flow) are used to measure the reaction kinetics of the reaction of CN (v = 1) with 1,3- and 1,2-butadiene isomers at low temperature.

Funder

National Science Foundation

Ministero dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/FD/D3FD00029J

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5. Detection of Ketenimine (CH 2 CNH) in Sagittarius B2(N) Hot Cores

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