Coordination of copper within a crystalline carbon nitride and its catalytic reduction of CO2

Author:

Pauly Magnus1,White Ethan1,Deegbey Mawuli1,Fosu Emmanuel Adu1,Keller Landon2,McGuigan Scott1,Dianat Golnaz2,Gabilondo Eric1,Wong Jian Cheng34,Murphey Corban G. E.3ORCID,Shang Bo5,Wang Hailiang5ORCID,Cahoon James F.3,Sampaio Renato3,Kanai Yosuke34,Parsons Gregory2ORCID,Jakubikova Elena1ORCID,Maggard Paul A.1ORCID

Affiliation:

1. North Carolina State University, Department of Chemistry, Raleigh, NC 27695, USA

2. North Carolina State University, Department of Chemical Engineering, Raleigh, NC 27695, USA

3. University of North Carolina-Chapel Hill, Department of Chemistry, Chapel Hill, NC 27599, USA

4. University of North Carolina-Chapel Hill, Departments of Physics and Astronomy, Chapel Hill, NC 27599, USA

5. Yale University, Department of Chemistry, New Haven, CT 06520, USA

Abstract

Crystallites of Cu-coordinated poly(triazine imide) were synthesized by flux methods and deposited from particle suspensions onto electrodes, yielding sizable current densities for the electrocatalytic reduction of CO2.

Funder

Basic Energy Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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