Local, solvation pressures and conformational changes in ethylenediamine aqueous solutions probed using Raman spectroscopy-Reference-Cited by-同舟云学术

Local, solvation pressures and conformational changes in ethylenediamine aqueous solutions probed using Raman spectroscopy

Published:2016 Issue:37 Volume:18 Page:26192-26198
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Cáceres Mercedes¹²³⁴⁵,Lobato Alvaro¹²³⁴⁵,Mendoza Nubia J.¹²³⁴⁵,Bonales Laura J.¹²³⁴⁵,Baonza Valentín G.¹²³⁴⁵

Affiliation:

1. MALTA-Consolider Team. Departamento de Química Física I

2. Facultad de Ciencias Químicas

3. Universidad Complutense de Madrid

4. 28040-Madrid

5. Spain

Abstract

Raman spectra of 1,2-ethylenediamine (EDA) in aqueous solutions are used to demonstrate that EDA molecules experience an anti–gauche conformational change resulting from the interactions with water.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP03857C

Reference33 articles.

1. Transverse Acoustic Modes of Biogenic and α,ω-Polyamines: A Study by Inelastic Neutron Scattering and Raman Spectroscopies Coupled to DFT Calculations

2. Structure and Rotational Isomerism of Ethylenediamine as Studied by Gas Electron Diffraction

3. Détermination de la structure cristalline de l'ethylènediamine, NH2–CH2–CH2–NH2, à –60°C

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