Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition-Reference-Cited by-同舟云学术

Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition

Published:2015 Issue:84 Volume:51 Page:15358-15361
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Long-Fei¹²³⁴⁵,Qiu Jiang-Zhen¹²³⁴⁵,Liu Jun-Liang¹²³⁴⁵^ORCID,Chen Yan-Cong¹²³⁴⁵,Jia Jian-Hua¹²³⁴⁵,Jover Jesús⁶⁷⁸⁹,Ruiz Eliseo⁶⁷⁸⁹,Tong Ming-Liang¹²³⁴⁵

Affiliation:

1. Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education

2. School of Chemistry & Chemical Engineering

3. Sun Yat-Sen University

4. 510275 Guangzhou

5. P. R. China

6. Departament de Química Inorgànica and Institut de Recerca de Química Teòrica i Computacional

7. Universitat de Barcelona

8. E-08028 Barcelona

9. Spain

Abstract

The first example of phototunable SMMs has been reported. Upon UV irradiation, the remarkable variations of the coordination sphere of Dy(iii) ions result in a magnetic transformation from the SMM behaviour to afield-induced slow relaxation via SCSC [2+2] cycloaddition reaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC07073B

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