Self-disproportionation of enantiomers of thalidomide and its fluorinated analogue via gravity-driven achiral chromatography: mechanistic rationale and implications-Reference-Cited by-同舟云学术

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Self-disproportionation of enantiomers of thalidomide and its fluorinated analogue via gravity-driven achiral chromatography: mechanistic rationale and implications

Published:2015 Issue:2 Volume:6 Page:1043-1048
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Maeno Mayaka¹²³⁴,Tokunaga Etsuko¹²³⁴,Yamamoto Takeshi¹²³⁴,Suzuki Toshiya⁵⁶⁷⁴,Ogino Yoshiyuki⁵⁶⁷⁴,Ito Emi¹²³⁴,Shiro Motoo⁸⁹¹⁰⁴,Asahi Toru⁵⁶⁷⁴,Shibata Norio¹²³⁴

Affiliation:

1. Department of Nanopharmaceutical Sciences and Department of Frontier Materials

2. Nagoya Institute of Technology

3. Nagoya 466-8555

4. Japan

5. Department of Life Science and Medical Bioscience

6. Waseda University (TWIns)

7. Tokyo 162-8480

8. Consolidated Research Institute for Advanced Science and Medical Care

9. Waseda University (ASMeW)

10. Tokyo 162-0041

Abstract

We report on the self-disproportionation of enantiomers of non-racemic thalidomide (1) and 3′-fluorothalidomide (2) under achiral chromatography.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC03047H

Reference85 articles.

1. THALIDOMIDE AND CONGENITAL ABNORMALITIES

2. Proposed mechanisms of action in thalidomide embryopathy

3. The evolution of thalidomide and its IMiD derivatives as anticancer agents

4. Thalidomide: dermatological indications, mechanisms of action and side-effects

5. The thalidomide saga

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