Effect of radical copolymerization of the (oxa)norbornene end-group of RAFT-prepared macromonomers on bottlebrush copolymer synthesis <i>via</i> ROMP-Reference-Cited by-同舟云学术

Effect of radical copolymerization of the (oxa)norbornene end-group of RAFT-prepared macromonomers on bottlebrush copolymer synthesis via ROMP

Published:2022 Issue:10 Volume:13 Page:1401-1410
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Naguib Mohamed¹²,Nixon Kate L.¹³,Keddie Daniel J.¹^ORCID

Affiliation:

1. School of Sciences, Faculty of Science and Engineering, University of Wolverhampton, Wulfruna Street, Wolverhampton, WV1 1LY, UK

2. Polymer and Pigments Department, National Research Centre, Cairo, 12622, Egypt

3. School of Life, Health and Chemical Sciences, The Open University, Walton Hall, Milton Keynes, MK7 6AA, UK

Abstract

Herein we demonstrate the effect that the structure of olefinic end-group (i.e. oxanorbornenyl vs norbornenyl) has upon the outcome of both macromonomer preparation by RAFT polymerization and subsequent bottlebrush polymer synthesis by ROMP.

Funder

Royal Society of Chemistry

University of Wolverhampton

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D1PY01599K

Reference33 articles.

1. Facile syntheses of cylindrical molecular brushes by a sequential RAFT and ROMP “grafting-through” methodology

2. Synthesis of Ultralarge Molecular Weight Bottlebrush Polymers Using Grubbs' Catalysts

3. Structure, function, self-assembly, and applications of bottlebrush copolymers

4. Fluorinated bottlebrush polymers based on poly(trifluoroethyl methacrylate): synthesis and characterization

5. Surface Properties of Bottlebrush Polymer Thin Films

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