A white phosphorescent coordination polymer with Cu2I2 alternating units linked by benzo-18-crown-6

Author:

Wu Fengshou12345,Tong Hongbo678,Li Zaoying123,Lei Wang91011,Liu Li1213141516,Wong Wai-Yeung4517,Wong Wai-Kwok4517,Zhu Xunjin4517

Affiliation:

1. College of Chemistry and Molecular Sciences

2. Wuhan University

3. Wuhan, P. R. China

4. Institute of Molecular Functional Materials and Department of Chemistry and Institute of Advanced Materials

5. Hong Kong Baptist University

6. Institute of Applied Chemistry

7. Shanxi University

8. Taiyuan, P. R. China

9. Wuhan National Laboratory for Optoelectronics

10. Huazhong University of Science and Technology

11. Wuhan 430074, P. R. China

12. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials

13. Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules

14. School of Chemistry and Chemical Engineering

15. Hubei University

16. Wuhan 430062, P. R. China

17. Hong Kong, P. R. China

Abstract

A 1D polymer of {[K(benzo-18-crown-6)]2(Cu2I4)}n with a Cu2I2 rhombus alternately connected by sandwich-like [K(benzo-18-crown-6)]2 displays direct white light in the solid state.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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