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Born–Oppenheimer approximation in optical cavities: from success to breakdown

  • Published:2021 Issue:4 Volume:12 Page:1251-1258
  • ISSN:2041-6520
  • Container-title:Chemical Science
  • language:en
  • Short-container-title:Chem. Sci.

Author:

Fábri Csaba12345ORCID,Halász Gábor J.6785ORCID,Cederbaum Lorenz S.910111213ORCID,Vibók Ágnes1478515ORCID

Affiliation:

1. Laboratory of Molecular Structure and Dynamics

2. Institute of Chemistry

3. Eötvös Loránd University

4. H-1117 Budapest

5. Hungary

6. Department of Information Technology

7. University of Debrecen

8. H-4002 Debrecen

9. Theoretische Chemie

10. Physikalisch-Chemisches Institut

11. Universität Heidelberg

12. 69120 Heidelberg

13. Germany

14. Department of Theoretical Physics

15. ELI-ALPS

Abstract

The coupling of a molecule and a cavity induces nonadiabaticity in the molecule which makes the description of its dynamics complicated.

Funder

Nemzeti Kutatási Fejlesztési és Innovációs Hivatal

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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1. Making molecules in cavity;The Journal of Chemical Physics;2024-08-15

2. Collective rovibronic dynamics of a diatomic gas coupled by cavity;Physical Review Research;2024-08-05

3. Coupling polyatomic molecules to lossy nanocavities: Lindblad vs Schrödinger description;The Journal of Chemical Physics;2024-06-05

4. Impact of Cavity on Molecular Ionization Spectra;The Journal of Physical Chemistry Letters;2024-04-22

5. Classical and quantum light-induced non-adiabaticity in molecular systems;AVS Quantum Science;2024-04-08
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