A visible-light mediated three-component radical process using dithiocarbamate anion catalysis-Reference-Cited by-同舟云学术

A visible-light mediated three-component radical process using dithiocarbamate anion catalysis

Published:2019 Issue:21 Volume:10 Page:5484-5488
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cuadros Sara¹²³⁴,Horwitz Matthew A.¹²³⁴,Schweitzer-Chaput Bertrand¹²³⁴^ORCID,Melchiorre Paolo¹²³⁴⁵^ORCID

Affiliation:

1. ICIQ – Institute of Chemical Research of Catalonia

2. The Barcelona Institute of Science and Technology

3. Tarragona

4. Spain

5. IIT – Istituto Italiano di Tecnologia

Abstract

A three-component radical process is reported that, by coupling alkyl chlorides, maleimides, and heteroaromatic fragments, installs multiple biologically relevant heterocycles within complex cascade products. This method, which generates radicals via an S_N2-based photochemical catalytic mechanism, activates substrates incompatible with or inert to classical radical-generating strategies.

Funder

H2020 European Research Council

Ministerio de Ciencia e Innovación

Agència de Gestió d’Ajuts Universitaris i de Recerca

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC00833K

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