A visible-light mediated three-component radical process using dithiocarbamate anion catalysis
Author:
Affiliation:
1. ICIQ – Institute of Chemical Research of Catalonia
2. The Barcelona Institute of Science and Technology
3. Tarragona
4. Spain
5. IIT – Istituto Italiano di Tecnologia
Abstract
A three-component radical process is reported that, by coupling alkyl chlorides, maleimides, and heteroaromatic fragments, installs multiple biologically relevant heterocycles within complex cascade products. This method, which generates radicals via an SN2-based photochemical catalytic mechanism, activates substrates incompatible with or inert to classical radical-generating strategies.
Funder
H2020 European Research Council
Ministerio de Ciencia e Innovación
Agència de Gestió d’Ajuts Universitaris i de Recerca
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC00833K
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