Synthesis and characterisation of homoleptic 2,9-diaryl-1,10-phenanthroline copper(i) complexes: influencing selectivity in photoredox-catalysed atom-transfer radical addition reactions

Author:

Nicholls Thomas P.1234,Caporale Chiara5674ORCID,Massi Massimiliano5674ORCID,Gardiner Michael G.1234ORCID,Bissember Alex C.1234ORCID

Affiliation:

1. School of Natural Sciences – Chemistry

2. University of Tasmania

3. Hobart

4. Australia

5. Department of Chemistry and Nanochemistry Research Institute

6. Curtin University

7. Bentley

Abstract

Novel bis(2,9-diaryl-1,10-phenanthroline)copper(i) complexes were prepared to study a photoredox-catalysed reaction.

Funder

University of Tasmania

Royal Australian Chemical Institute

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference80 articles.

1. Photoactive mono- and polynuclear Cu(i)–phenanthrolines. A viable alternative to Ru(ii)–polypyridines?

2. N. Armaroli , G.Accorsi , F.Cardinali and A.Listorti , Photochemistry and Photophysics of Coordination Compounds: Copper , in Topics in Current Chemistry 280 , ed. V. Balzani and S. Campagna , Springer , Berlin, Germany , 2007 , pp. 69–116

3. Improving the photophysical properties of copper(I) bis(phenanthroline) complexes

4. Copper in Photocatalysis

5. Heteroleptic Cu-Based Sensitizers in Photoredox Catalysis

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