Triple decker sandwiches and related compounds of the first row transition metals with cyclopentadienyl and hexafluorobenzene rings: remarkable effects of fluorine substitution-Reference-Cited by-同舟云学术

Triple decker sandwiches and related compounds of the first row transition metals with cyclopentadienyl and hexafluorobenzene rings: remarkable effects of fluorine substitution

Published:2015 Issue:31 Volume:17 Page:20100-20113
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Gong Shida¹²³⁴⁵,Luo Qiong¹²³⁴⁵,Feng Xiangfei¹²³⁴⁵,Li Qian-shu¹²³⁴⁵,Xie Yaoming⁶⁷⁸⁹,King R. Bruce¹²³⁴⁵,Schaefer III Henry F.⁶⁷⁸⁹

Affiliation:

1. MOE Key Laboratory of Theoretical Chemistry of the Environment

2. Center for Computational Quantum Chemistry

3. South China Normal University

4. Guangzhou 510631

5. P. R. China

6. Department of Chemistry and Center for Computational Chemistry

7. University of Georgia

8. Athens

9. USA

Abstract

The early transition metals Ti and V energetically prefer the triple decker sandwichtrans-Cp₂M₂(η⁶,η⁶-μ-C₆F₆) structures. The later transition metals from Cr to Ni prefer the so-called “rice-ball”cis-Cp₂M₂(μ-C₆F₆) structures.

Funder

Division of Chemistry

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP01648G

Reference51 articles.

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3. Di-benzol-chrom

4. Über Aromatenkomplexe von Metallen, XCII. Über Fünfring‐Sechsring‐Aromaten‐Metall‐π‐Komplexe des Chroms und Mangans und ihr anomales Verhalten bei Acylierungsversuchen nach Friedel‐Crafts

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