A green route to polyurethanes: oxidative carbonylation of industrially relevant aromatic diamines by CO2-based methyl formate-Reference-Cited by-同舟云学术

A green route to polyurethanes: oxidative carbonylation of industrially relevant aromatic diamines by CO2-based methyl formate

Published:2020 Issue:23 Volume:22 Page:8260-8270
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Hussong Christine¹²³⁴,Langanke Jens¹²³⁴⁵,Leitner Walter¹²³⁴⁶^ORCID

Affiliation:

1. RWTH Aachen University

2. CAT Catalytic Center

3. 52074 Aachen

4. Germany

5. Covestro Deutschland AG

6. Max Planck Institute for Chemical Energy Conversion

Abstract

Toluene-2,4-diamine, 4,4′-methylenedianiline and 2,4-diaminomesitylene were converted directly into the corresponding dicarbamates via the CO₂-based intermediate methyl formate (MF) which can be regarded as a liquid source for CO/MeOH mixtures.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/GC/D0GC02412K

Reference83 articles.

1. Designing for a green chemistry future

2. C. Six and F.Richter , Isocyanates, Organic , in Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH Verlag , Weinheim , 2000

3. Reaction Path of One-Pot Synthesis of Methyl N-Phenyl Carbamate from Aniline, Urea, and Methanol

4. A new non-phosgene route for synthesis of methyl N-phenyl carbamate from phenylurea and methanol

5. Synthesis of methyl N-phenyl carbamate from dimethyl carbonate and 1,3-diphenyl urea under mild conditions

Cited by 12 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Green process for Polyurethane: From CO2 to isocyanate;Chemical Engineering Journal;2024-08

2. Ring-Opening Polymerization of Cyclohexene Oxide and Cycloaddition with CO2 Catalyzed by Amine Triphenolate Iron(III) Complexes;Molecules;2024-05-04

3. Benign synthesis of terpene-based 1,4-p-menthane diamine;Scientific Reports;2024-04-05

4. A dual-functional catalyst for selective dicarbamate synthesis via oxidative carbonylation: enhanced methoxylation for suppressing urea polymer formation;Green Chemistry;2024

5. On the metal- and bio-catalyzed solvolysis of polyesters and polyurethanes wastes;RSC Sustainability;2024