Coplanar binuclear group 4 post-metallocene complexes supported by chelating μ-(σ<sub>2</sub>-aryl) ligands: characterisation and olefin polymerisation catalysis-Reference-Cited by-同舟云学术

Coplanar binuclear group 4 post-metallocene complexes supported by chelating μ-(σ₂-aryl) ligands: characterisation and olefin polymerisation catalysis

Published:2024 Issue:1 Volume:53 Page:346-353
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Li Yufang¹^ORCID,Liu Qian¹,Bao Junhui¹^ORCID,Yiu Shek-Man¹^ORCID,Chan Michael C. W.¹^ORCID

Affiliation:

1. Department of Chemistry and Department of Materials Science and Engineering, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China

Abstract

Rigid binuclear assemblies with M⋯M distances and syn binding sites that are amenable for cooperative reactivity have been structurally characterised; the Ti2 catalysts are more active than anti and mono-Ti controls and produced higher-Mw polymers.

Funder

Research Grants Council, University Grants Committee

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03641C

Reference59 articles.

1. Binuclear Metallohydrolases: Complex Mechanistic Strategies for a Simple Chemical Reaction

2. Cooperative multimetallic catalysis using metallosalens

3. Bimetallics in a Nutshell: Complexes Supported by Chelating Naphthyridine-Based Ligands

4. Multinuclear Olefin Polymerization Catalysts

5. Recent progress in olefinpolymerization catalyzed by transition metal complexes: new catalysts and new reactions

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