Base-free transfer hydrogenation of aldehydes and ketones catalyzed by imidazolin-2-iminato actinide complexes

Author:

Deka Hemanta1,Fridman Natalia1,Koneczny Marvin2,Tamm Matthias2ORCID,Eisen Moris S.1ORCID

Affiliation:

1. Schulich Faculty of Chemistry, Technion − Israel Institute of Technology, Technion City, Haifa, 3200008, Israel

2. Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Brauschweig, Germany

Abstract

A series of thorium and uranium complexes decorated with unsymmetrical imidazolin-2-iminato ligands were found to be effective as catalysts in the transfer hydrogenation of aldehydes and ketones with 2-propanol to form the corresponding alcohols.

Funder

Israel Science Foundation

PAZY Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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