C–N bond metathesis: mechanistic insight into palladium-catalyzed ring-closing using aminal species

Author:

Liu Song123ORCID,Zhang Dianmin1,Xiao Min1,Pu Chengling1,Zhang Xiaoqing1,Yang Xiuwen1,Zhang Tao4,Bai Ruopeng2ORCID

Affiliation:

1. Chongqing Key Laboratory of Environmental Materials and Remediation Technologies, College of Chemistry and Environmental Engineering, Chongqing University of Arts and Sciences, Chongqing, 402160, P. R. China

2. School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, China

3. Chongqing Precision Medical Industry Technology Research Institute, Chongqing 400084, P. R. China

4. ZhengZhou JiShu Institute of AI Science, Zhengzhou, Henan, China 450000

Abstract

A computational study was conducted to investigate the mechanism of a new type of C–N bond metathesis reaction, in which a reversible reductive elimination/oxidative addition mode is involved.

Funder

Chongqing Science and Technology Commission

Chongqing University of Arts and Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference48 articles.

1. S. A.Lawrence , Amines: Synthesis, Properties and Applications , Cambridge Univ. Press , 2004

2. A.Ricci , Amino Group Chemistry: From Synthesis to the Life Sciences , Wiley , 2008

3. Nickel-catalyzed hydrogenative coupling of nitriles and amines for general amine synthesis

4. Toward Amines, Imines, and Imidazoles: A Viewpoint on the 3d Transition-Metal-Catalyzed Homogeneous Hydrogenation of Nitriles

5. Transition-Metal-Catalyzed Reductive Amination Employing Hydrogen

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