Visible-light-photocatalysis driven denitrogenative/radical 1,3-shift of benzotriazole: access to 3-aryl-aminoquinoxalin-2(1<i>H</i>)-one scaffolds-Reference-Cited by-同舟云学术

Visible-light-photocatalysis driven denitrogenative/radical 1,3-shift of benzotriazole: access to 3-aryl-aminoquinoxalin-2(1H)-one scaffolds

Published:2023 Issue:2 Volume:10 Page:531-539
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Yi Bing¹,Tang Huan²,Yi Ziqi³,Gong Huiling¹,Li Daiguang¹,Zhang Wenhui²,Chen Yizheng¹,Tan Jian-Ping¹^ORCID,Xie Yanjun¹^ORCID

Affiliation:

1. Hunan Province Key Laboratory of Environmental Catalysis and Waste Recycling College of Materials and Chemical Engineering Hunan Institute of Engineering Xiangtan, 411104, P. R. China

2. College of Chemistry Xiangtan University Xiangtan, 411105, P. R. China

3. CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences Beijing, 100190, P. R. China

Abstract

We described a visible-light-photocatalysis driven denitrogenative/radical 1,3-shift of benzotriazole to generate unusual aromatic amine radical which then undergo direct amination with quinoxalin-2(1H)-ones leading to 3-aryl-aminoquinoxalin-2(1H)-ones.

Funder

Key Project of Research and Development Plan of Hunan Province

Natural Science Foundation ofHunan Province

Education Department of Hunan Province

Science and Technology Program of Hunan Province

Hunan Provincial Postdoctoral Science Foundation

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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