Hydrogen spillover on Rh/TiO2: the FTIR study of donated electrons, co-adsorbed CO and H/D exchange-Reference-Cited by-同舟云学术

Hydrogen spillover on Rh/TiO2: the FTIR study of donated electrons, co-adsorbed CO and H/D exchange

Published:2015 Issue:32 Volume:17 Page:20563-20573
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Panayotov D.¹²³⁴,Ivanova E.¹²³⁴,Mihaylov M.¹²³⁴,Chakarova K.¹²³⁴,Spassov T.⁵⁶⁷⁴,Hadjiivanov K.¹²³⁴

Affiliation:

1. Institute of General and Inorganic Chemistry

2. Bulgarian Academy of Sciences

3. Sofia 1113

4. Bulgaria

5. University of Sofia

6. Department of Chemistry and Pharmacy

7. Sofia 1126

Abstract

Hydrogen spillover on Rh/TiO₂: molecular H₂ dissociates on nanocrystalline Rh; the produced H atoms spillover onto the titania thus protonating the semiconductor, while donating electrons to shallow trap (ST) states and the conduction band (CB) of TiO₂.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP03148F

Reference79 articles.

1. Adlineation, Portholes and Spillover

2. Second international conference on spillover

3. Spillover in Heterogeneous Catalysis

4. Hydrogen Spillover. Facts and Fiction

5. Kinetic Evidence for the Migration of Reactive Intermediates in Surface Catalysis

Cited by 37 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Hydrogen Spillover Is Regulating Minority Rh₁ Active Sites on TiO₂ in Room-Temperature Ethylene Hydrogenation;ACS Catalysis;2024-04-26

2. Unravelling structure sensitivity in heterogeneous hydroformylation of aldehyde over Rh;Chemical Engineering Journal;2024-02

3. Hydrogen spillover as a promising strategy for boosting heterogeneous catalysis and hydrogen storage;Chemical Engineering Journal;2023-09

4. Rapid Joule Heating Synthesis of Oxide-Socketed High-Entropy Alloy Nanoparticles as CO₂ Conversion Catalysts;ACS Nano;2023-05-25

5. Synergetic effect of Ce/Zr for ethanol synthesis from syngas over Rh-based catalyst;Fuel;2023-02