N-Haloimide-enabled halogenation via halogen-bond-assisted C–C activation of alkanols

Author:

Geng Yan1,Ma Yue1,Huang Rui1,Li Xingwei2,Yu Songjie12ORCID

Affiliation:

1. Zhang Dayu School of Chemistry, Dalian University of Technology, Dalian, China

2. Institute of Molecular Science and Engineering, Institute of Frontier and Interdisciplinary Sciences, Shandong University, Qingdao, China

Abstract

The halogen-bond-assisted C–C activation of alkanols to synthesize a library of alkyl halides in the absence of catalysts and oxidants is disclosed, wherein inexpensive N-haloimides were explored as bifunctional reagents.

Funder

Fundamental Research Funds for the Central Universities

Taishan Scholar Foundation of Shandong Province

Shandong University

Dalian University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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