Ti3+ self-doped TiO2−x nanowires for efficient electrocatalytic N2 reduction to NH3-Reference-Cited by-同舟云学术

Ti3+ self-doped TiO2−x nanowires for efficient electrocatalytic N2 reduction to NH3

Published:2020 Issue:7 Volume:56 Page:1074-1077
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Bingyue¹²³⁴⁵,Zhu Xiaojuan¹²³⁴⁶,Wang Jianwei⁷²⁸⁴,Xing Ruimin⁵⁹¹⁰¹¹¹²,Liu Qian¹²³⁴^ORCID,Shi Xifeng¹³¹⁴¹⁵¹⁶⁴,Luo Yonglan⁶¹⁰¹⁷¹⁸⁴^ORCID,Liu Shanhu⁵⁹¹⁰¹¹¹²,Niu Xiaobin⁷²⁸⁴^ORCID,Sun Xuping¹²³⁴^ORCID

Affiliation:

1. Institute of Fundamental and Frontier Sciences

2. University of Electronic Science and Technology of China

3. Chengdu 610054

4. China

5. Henan Key Laboratory of Polyoxometalate Chemistry

6. Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province

7. School of Materials and Energy

8. Chengdu 611731

9. Henan Joint International Research Laboratory of Environmental Pollution Control Materials

10. College of Chemistry and Chemical Engineering

11. Henan University

12. Kaifeng 47504

13. College of Chemistry

14. Chemical Engineering and Materials Science

15. Shandong Normal University

16. Jinan 250014

17. China West Normal University

18. Nanchong 637002

Abstract

Ti³⁺–TiO_2−x/TM behaves as an efficient electrocatalyst for ambient N₂-to-NH₃ fixation with a high faradaic efficiency of 14.62% and a NH₃ yield of 3.51 × 10⁻¹¹ mol s⁻¹ cm⁻² at −0.55 V versus a reversible hydrogen electrode in 0.1 M Na₂SO₄.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC08971C

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4. Transformation of Coordinated Dinitrogen by Reaction with Dihydrogen and Primary Silanes

5. I. Dybkjaer , Ammonia, Catalysis and Manufacture , ed. A. Nielsen , Springer , Heidelberg , 1995 , pp. 199–308

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