Real-time observation of ultrafast electron injection at graphene–Zn porphyrin interfaces

Author:

Masih Dilshad12345,Aly Shawkat M.12345,Usman Anwar12345,Alarousu Erkki12345,Mohammed Omar F.12345

Affiliation:

1. Solar and Photovoltaics Engineering Research Center

2. Division of Physical Sciences and Engineering

3. King Abdullah University of Science and Technology

4. Thuwal 23955-6900

5. Kingdom of Saudi Arabia

Abstract

Femtosecond transient absorption spectra of zinc(ii) porphyrin in the presence of graphene carboxylate (GC) reveal ultrafast electron transfer from the singlet excited ZnTMPyP* to GC, forming ZnTMPyP˙+ and GC˙ radical ion pairs.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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