New tetranuclear manganese clusters with [MnII3MnIII] and [MnII2MnIII2] metallic cores exhibiting low and high spin ground state-Reference-Cited by-同舟云学术

New tetranuclear manganese clusters with [MnII3MnIII] and [MnII2MnIII2] metallic cores exhibiting low and high spin ground state

Published:2016 Issue:17 Volume:45 Page:7303-7311
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sobocińska M.¹²³⁴,Antkowiak M.⁵⁶⁷⁴,Wojciechowski M.⁸⁹¹⁰⁴,Kamieniarz G.⁵⁶⁷⁴,Utko J.¹²³⁴,Lis T.¹²³⁴

Affiliation:

1. Faculty of Chemistry

2. University of Wrocław

3. Wrocław

4. Poland

5. Faculty of Physics

6. A. Mickiewicz University

7. Poznań

8. Institute of Physics

9. University of Zielona Góra

10. 65-516 Zielona Góra

Abstract

Two tetranuclear mixed-valent clusters with the metallic [MnII3Mn^III] and [MnII2MnIII2] cores were synthesized as molecular nanomagnets with the low and high spin in the ground state.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04869A

Reference57 articles.

1. Heptanuclear and Decanuclear Manganese Complexes with the Anion of 2-Hydroxymethylpyridine

2. A Dimeric Manganese(III) Tetradentate Schiff Base Complex as a Single-Molecule Magnet

3. High-spin molecules: [Mn12O12(O2CR)16(H2O)4]

4. Rational design of single-molecule magnets: a supramolecular approach

5. Synthesis, structure and magnetism of new single molecule magnets composed of MnII2MnIII2 alkoxo-carboxylate bridged clusters capped by triethanolamine ligandsElectronic supplementary information (ESI) available: Detailed magnetisation discussion, Mn bond valence sums (Table S1), H-bonding details (Table S2). See http://www.rsc.org/suppdata/dt/b3/b312672b/

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