Ring opening polymerisation of lactide with uranium(iv) and cerium(iv) phosphinoaryloxide complexes-Reference-Cited by-同舟云学术

Ring opening polymerisation of lactide with uranium(iv) and cerium(iv) phosphinoaryloxide complexes

Published:2017 Issue:33 Volume:46 Page:10786-10790
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sinclair Fern¹²³⁴⁵,Hlina Johann A.¹²³⁴⁵,Wells Jordann A. L.¹²³⁴⁵,Shaver Michael P.¹²³⁴⁵^ORCID,Arnold Polly L.¹²³⁴⁵^ORCID

Affiliation:

1. EaStCHEM School of Chemistry

2. Joseph Black Building

3. University of Edinburgh

4. Edinburgh EH9 3FJ

5. UK

Abstract

The C₃-symmetric uranium(iv) and cerium(iv) complexes Me₃SiOM(OAr^P)₃, M = U (1), Ce (2), OAr^P = OC₆H₂-6-^tBu-4-Me-2-PPh₂, have been prepared and the difference between these 4f and 5f congeners as initiators for the ring opening polymerisation (ROP) of l-lactide is compared.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02167D

Reference19 articles.

1. From Lactic Acid to Poly(lactic acid) (PLA): Characterization and Analysis of PLA and Its Precursors

2. Polymers from Renewable Resources: A Perspective for a Special Issue of Polymer Reviews

3. The Path Forward for Biofuels and Biomaterials

4. Synthesis and characterisation of unsymmetrical Zr(iv) amine tris(phenolate) complexes and their application in ROP of rac-LA

5. Highly active and stereoselective zirconium and hafnium alkoxide initiators for solvent-free ring-opening polymerization of rac-lactide

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