An anionic heterosiliconoid with two germanium vertices-Reference-Cited by-同舟云学术

An anionic heterosiliconoid with two germanium vertices

Published:2019 Issue:68 Volume:55 Page:10100-10103
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Klemmer Lukas¹²³⁴^ORCID,Huch Volker¹²³⁴,Jana Anukul⁵⁶⁷^ORCID,Scheschkewitz David¹²³⁴^ORCID

Affiliation:

1. Krupp-Chair of General and Inorganic Chemistry

2. Saarland University

3. 66123 Saarbrücken

4. Germany

5. Tata Institute of Fundamental Research Hyderabad

6. Hyderabad-500107

7. India

Abstract

Reduction of dismutational 1,4-digermatetrasilabenzene isomer gives lithium digermatetrasila-benzpolarenide (R = Tip = 2,4,6-iPr₃C₆H₂). The positions of its Ge vertices yield mechanistic insights; its reaction with SiCl₄ proves its nucleophilicity.

Funder

Alexander von Humboldt-Stiftung

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC04576G

Reference51 articles.

1. Stable unsaturated silicon clusters (siliconoids)

2. Surface Chemistry of Silicon

3. A Molecular Silicon Cluster with a “Naked” Vertex Atom

4. The Cp*Si+ cation as a stoichiometric source of silicon

5. A Tricyclic Aromatic Isomer of Hexasilabenzene

Cited by 22 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Tetrylene-Functionalized Si₇–Siliconoids;Inorganic Chemistry;2024-03-19

2. Installing Quaternary Germanium Centers in Sila-Diamondoid Cores via Skeletal Isomerization;Journal of the American Chemical Society;2023-09-08

3. X‐ray Crystallography of Organogermanium Compounds;Organogermanium Compounds;2023-03-15

4. Germaaromatic Compounds;Organogermanium Compounds;2023-03-15

5. Germanium‐Centered Anions;Organogermanium Compounds;2023-03-15