Supercritical fluid-assisted modification combined with the resynthesis of SmCoO3 as an effective tool to enhance the long-term performance of SmCoO3-derived catalysts for the dry reforming of methane to syngas

Author:

Gavrikov Andrey V.1ORCID,Loktev Alexey S.123ORCID,Ilyukhin Andrey B.1,Mukhin Igor E.2,Bykov Mikhail A.4,Maslakov Konstantin I.4ORCID,Vorobei Anton M.1ORCID,Parenago Olga O.1,Sadovnikov Alexey A.13,Dedov Alexey G.123

Affiliation:

1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

2. National University of Oil and Gas “Gubkin University”, Moscow, Russian Federation

3. A.V. Topchiev Institute of Petrochemical Synthesis, RAS, Moscow, Russian Federation

4. Department of Chemistry, Lomonosov Moscow State University, Moscow, Russian Federation

Abstract

For the first time, the effect of supercritical fluids-assisted modification of the SmCoO3 precursor combined with the re-oxidation of spent catalysts to SmCoO3 onto its long-term performance in dry reforming of methane to Syngas is revealed.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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