A new pnictidehalide with van der Waals host–guest interactions exhibiting both geometric spin frustration and resistive humidity sensitivity

Author:

Peng Si-Yan12345ORCID,Yang Liu-Sai123,Yao Ming-Shui453,Yu Le-Shu123

Affiliation:

1. School of Chemistry and Environmental Science, Shangrao Normal University

2. Shangrao

3. P. R. China

4. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou

5. Fujian 350002

Abstract

The structure and electric and magnetic properties of a new metal pnictidehalide (Hg6P4)(CrCl6)Cl are reported in detail. The weak van der Waals interactions in its structure are responsible for its geometric spin frustration and good resistive humidity sensitivity.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangxi Province

Chinese Academy of Sciences

Natural Science Foundation of Fujian Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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