Determining the Q–e values of polymer radicals and monomers separately through the derivation of an intrinsic Q–e scheme for radical copolymerization-Reference-Cited by-同舟云学术

Determining the Q–e values of polymer radicals and monomers separately through the derivation of an intrinsic Q–e scheme for radical copolymerization

Published:2022 Issue:8 Volume:13 Page:1116-1129
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Kawauchi Susumu¹²³^ORCID,Akatsuka Akinori²,Hayashi Yoshihiro²³⁴^ORCID,Furuya Hidemine²³^ORCID,Takata Toshikazu²³⁵^ORCID

Affiliation:

1. Tokyo Tech Academy for Convergence of Materials and Informatics (TAC-MI), Tokyo Institute of Technology, S6-23, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan

2. Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan

3. Research Institute of Polymer Science and Technology (RIPST), Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan

4. Research Organization of Information and Systems, The Institute of Statistical Mathematics, 10-3 Midori-cho, Tachikawa, Tokyo 190-8562, Japan

5. Graduate School of Advanced Science and Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8527, Japan

Abstract

To non-arbitrarily determine the Q–e values for individual polymer radicals and monomers, a new scheme, i.e., the intrinsic Q–e scheme, was derived by subjecting the two reference monomers to the generalized Q–e scheme including individual radical and monomer parameters.

Funder

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D1PY01190A

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