Controllable access to P-functional [3]ferrocenophane and [4]ferrocenophane frameworks

Author:

Weller Stefan1234,Schlindwein Simon H.1234,Feil Christoph M.1234,Kelemen Zsolt56789ORCID,Buzsáki Dániel56789ORCID,Nyulászi László56789ORCID,Isenberg Stefan1011124,Pietschnig Rudolf1011124ORCID,Nieger Martin1314151617ORCID,Gudat Dietrich1234ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. University of Stuttgart

3. 70550 Stuttgart

4. Germany

5. Department of Inorganic and Analytical Chemistry

6. Budapest University of Technology and Economics

7. and MTA-BME Computation Driven Chemistry Research Group

8. 1111 Budapest

9. Hungary

10. Institut für Chemie und CINSaT

11. Universität Kassel

12. 34132 Kassel

13. Department of Chemistry

14. University of Helsinki

15. P.O Box 55

16. 00014 University of Helsinki

17. Finland

Abstract

Condensation of 1,1′-diaminoferrocenes with PCl3 gives access to P-halo-diazaphospha-[3]ferrocenophanes and [4]ferrocenophane-annelated tetraphosphetanes, which can undergo multiple oxidation in both ferrocene and aminophosphine units.

Funder

Alexander von Humboldt-Stiftung

Országos Tudományos Kutatási Alapprogramok

European Cooperation in Science and Technology

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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