Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

Author:

Roy Sudipta Raha12345,Eijsberg Hendrik12345,Bruffaerts Jeffrey12345,Marek Ilan12345

Affiliation:

1. The Mallat Family Laboratory of Organic Chemistry

2. Schulich Faculty of Chemistry and Lise Meitner-Minerva Center for Computational Quantum Chemistry

3. Technion-Israel Institute of Technology

4. Haifa 32000

5. Israel

Abstract

We functionalize cyclobutene species into polysubstituted metalated cyclobutanes through the Dzhemilev reaction.

Funder

Israel Academy of Sciences and Humanities

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference89 articles.

1. I. Marek and A.Basheer, in Stereoselective Synthesis; Science of Synthesis, ed. J. G. de Vries, Thieme, 2011, p. 325

2. K. Itami and J.-I.Yoshida, in The Chemistry of Organomagnesium Compounds, ed. Z. Rappoport and I. Marek, Wiley, Chichester, 2008

3. Metal mediated carbometallation of alkynes and alkenes containing adjacent heteroatoms

4. I. Marek and J.-F.Normant, in Metal-Catalyzed Cross-Coupling Reactions, ed. P. J. Stang and F. Diederich, Wiley-VCH, Weinheim, 1998, p. 271

5. N. Chinkov , D.Tenne and I.Marek, in Metal-Catalyzed Cross-Coupling Reactions, ed. F. Diederich and A. de Meijere, Wiley-VCH, Weinheim, 2004, p. 395

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