Metal-free C(sp3)–H bond sulfonyloxylation of 2-alkylpyridines and alkylnitrones
Author:
Affiliation:
1. Univ Rennes
2. CNRS UMR6226
3. F-3500 Rennes
4. France
Abstract
Direct transformation of an inert C(sp3)–H bond of 2-alkylpyridines and nitrones into a C–OSO2R bond has been described.
Funder
China Scholarship Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB01075G
Reference36 articles.
1. Complementary Strategies for Directed C(sp3)−H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer
2. Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds
3. Transition metal-catalyzed direct remote C–H functionalization of alkyl groups via C(sp3)–H bond activation
4. Diverse sp3 C−H functionalization through alcohol β-sulfonyloxylation
5. Molecular recognition and indicator-displacement assays for phosphoesters
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