Dominant formation of disulfidic linkages in the sulfur cross-linking reaction of isoprene rubber by using zinc stearate as an activator

Author:

Sakaki Yuta1234,Usami Ryota1234,Tohsan Atitaya56789,Junkong Preeyanuch1023411,Ikeda Yuko1023412ORCID

Affiliation:

1. Graduate School of Science and Technology

2. Kyoto Institute of Technology

3. Kyoto 606-8585

4. Japan

5. Department of Materials and Production Technology Engineering

6. Faculty of Engineering

7. King Mongkut's University of Technology North Bangkok

8. Bangkok 10800

9. Thailand

10. Center for Rubber Science and Technology

11. Research Strategy Promotion Center

12. Faculty of Molecular Chemistry and Engineering

Abstract

The bridging bidentate zinc/stearate complex, an intermediate for the sulfur cross-linking reaction, supposedly induces an abundance of disulfidic linkages in the rubber network.

Funder

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference40 articles.

1. J. L.Bras , Rubber: Fundamentals of Its Science and Technology , Chemical Publishing Company , New York , 1957

2. A. K.Bhowmick , Rubber Products Manufacturing Technology , CRC Press , USA , 1994

3. J. L.White , Rubber Processing: Technology, Materials , Hanser Publishers , Germany , 1995

4. A.Ciesielski , An Introduction to Rubber Technology , iSmithers Rapra Publishing , USA , 1999

5. A. Y.Coran , The Science and Technology of Rubber , Academic Press , San Diego , 2nd edn, 1994

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