Biomimics of [FeFe]-hydrogenases incorporating redox-active ligands: synthesis, redox properties and spectroelectrochemistry of diiron-dithiolate complexes with ferrocenyl-diphosphines as Fe<sub>4</sub>S<sub>4</sub> surrogates-Reference-Cited by-同舟云学术

Biomimics of [FeFe]-hydrogenases incorporating redox-active ligands: synthesis, redox properties and spectroelectrochemistry of diiron-dithiolate complexes with ferrocenyl-diphosphines as Fe₄S₄ surrogates

Published:2022 Issue:25 Volume:51 Page:9748-9769
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Orton Georgia R. F.¹,Ghosh Shishir¹²,Alker Lucy²,Sarker Jagodish C.¹,Pugh David¹^ORCID,Richmond Michael G.³^ORCID,Hartl František⁴^ORCID,Hogarth Graeme¹^ORCID

Affiliation:

1. Department of Chemistry, King's College London, 7 Trinity Street, London, SE1 1DB, UK

2. Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, UK

3. Department of Chemistry, University of North Texas, 1155 Union Circle, Box 305070, Denton, Texas 76203, USA

4. Department of Chemistry, University of Reading, Whiteknights, Reading RG6 6DX, UK

Abstract

Ferrocenyl diphosphine bridged diiron dithiolate complexes have been prepared and their redox properties investigated by CV and IR SEC supported by DFT calculations to give insight into their proton reduction and hydrogen oxidation activity.

Funder

Commonwealth Scholarship Commission

King’s College London

Royal Society of Chemistry

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00419D

Reference84 articles.