Materials design, synthesis, and transport properties of disordered rare-earth Zintl bismuthides with the anti-Th3P4 structure type

Author:

Ogunbunmi Michael O.1ORCID,Baranets Sviatoslav1ORCID,Bobev Svilen1ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA

Abstract

The synthesis, structural elucidation, and transport properties of the extended series Ca4−xRExBi3 (RE = Y, La–Nd, Sm, Gd–Tm, and Lu; x ≈ 1) and Ca4−xRExBi3−δSbδ (RE = La, Ho, Er, and Lu; x ≈ 1, δ ≈ 1.5) are presented.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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