The decomposition of benzenesulfonyl azide: a matrix isolation and computational study-Reference-Cited by-同舟云学术

The decomposition of benzenesulfonyl azide: a matrix isolation and computational study

Published:2017 Issue:5 Volume:19 Page:3792-3799
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Deng Guohai¹²³⁴⁵,Dong Xuelin¹²³⁴⁵,Liu Qifan¹²³⁴⁵,Li Dingqing¹²³⁴⁵,Li Hongmin¹²³⁴⁵,Sun Qiao⁶³⁴⁵,Zeng Xiaoqing¹²³⁴⁵^ORCID

Affiliation:

1. College of Chemistry

2. Chemical Engineering and Materials Science

3. Soochow University

4. 215123 Suzhou

5. P. R. China

6. School for Radiological and Interdisciplinary Sciences

Abstract

The stepwise Curtius-rearrangement of benzenesulfonyl azide, PhS(O)₂N₃, has been proven experimentally by the direct observation of the novel intermediates sulfonyl nitrene PhS(O)₂N and N-sulfonyl imine PhNSO₂ and theoretically by quantum chemical calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C6CP08125H

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