Copper–nitroxide based breathing crystals: a unified mechanism of gradual magnetostructural transition supported by quantum chemistry calculations
Author:
Affiliation:
1. Departamento de Química Física. Universidad de Sevilla
2. Spain
3. Departamento de Física Aplicada I
4. Escuela Politécnica Superior
5. Universidad de Sevilla
Abstract
A unified mechanism, based on the thermal average of two limit phases, governs the gradual magnetic transitions of Cu(hfac)2LR complexes.
Funder
Ministerio de Economía y Competitividad
European Regional Development Fund
Universidad de Sevilla
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QI/C9QI00129H
Reference50 articles.
1. Electron paramagnetic resonance of switchable copper-nitroxide-based molecular magnets: An indispensable tool for intriguing systems
2. Thermally Induced Spin Transitions in Nitroxide−Copper(II)−Nitroxide Spin Triads Studied by EPR
3. High-Field EPR Reveals the Strongly Temperature-Dependent Exchange Interaction in “Breathing” Crystals Cu(hfac)2LR
4. Light-Induced Excited Spin State Trapping in an Exchange-Coupled Nitroxide-Copper(II)-Nitroxide Cluster
5. Dynamic mixing processes in spin triads of “breathing crystals” Cu(hfac)2LR: a multifrequency EPR study at 34, 122 and 244 GHz
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