Unexpected structural preference with metallophilic Ag–Au contacts in silver(<scp>i</scp>)-N-heterocyclic carbene cluster; experimental and theoretical approach-Reference-Cited by-同舟云学术

Unexpected structural preference with metallophilic Ag–Au contacts in silver(i)-N-heterocyclic carbene cluster; experimental and theoretical approach

Published:2024 Issue:3 Volume:53 Page:1099-1104
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sahu Priyanka¹,Jana Narayan Ch.²^ORCID,Barik Sahadev²,Kisan Hemanta K.³,Changotra Avtar⁴,Isab Anvarhusein A.⁵^ORCID,Dinda Joydev¹^ORCID

Affiliation:

1. Department of Chemistry, Utkal University, Bhubaneswar-751004, Odisha, India

2. School of Chemical Sciences, National Institute of Science Education and Research, HBNI, Bhubaneswar, Odisha, 752050, India

3. Department of Chemistry, Indian Institute of Technology Bhilai, GEC Campus, Sejbahar, Raipur-492015, Chhattisgarh, India

4. School of Science, Department of Chemistry, Cluster University of Jammu, Jammu-180001, India

5. Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia

Abstract

Substoichiometric transmetallation of an Ag3-NHC cluster leads to an Ag2Au-NHC cluster that bears strong metallophilic Ag–Au contacts; the aromaticity in these clusters has been explored.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT02551A

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4. Synthesis and Characterization of Heterobimetallic Carbonyl Clusters with Direct Au‐Fe and Au···Au Interactions Supported by N ‐Heterocyclic Carbene and Phosphine Ligands

5. Bimetallic Co–M (M = Cu, Ag, and Au) Carbonyl Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis, Structures, Computational Investigation, and Catalysis for Ammonia Borane Dehydrogenation

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