Step-by-step synthesis of one Fe6 wheel and two Fe10 clusters derived from a multidentate triethanolamine ligand

Author:

Liu Sui-Jun12345,Han Song-De12345,Jia Ji-Min12345,Xue Li12345,Cui Yu12345,Zhang Shu-Ming675,Chang Ze12345

Affiliation:

1. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education)

2. Department of Chemistry

3. TKL of Metal- and Molecule-Based Material Chemistry and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)

4. Nankai University

5. , PR China

6. School of Chemical Engineering and Technology

7. Hebei University of Technology

Abstract

One Fe6 wheel and two Fe10 clusters based on multidentate triethanolamine have been prepared with step-by-step strategy and structurally characterized. Magnetic analyses indicate that the Fe6 wheel exhibits strong antiferromagnetic behavior with S = 0 ground state.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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