Zinc complexes bearing BIAN ligands as efficient catalysts for the formation of cyclic carbonates from CO<sub>2</sub> and epoxides-Reference-Cited by-同舟云学术

Zinc complexes bearing BIAN ligands as efficient catalysts for the formation of cyclic carbonates from CO₂ and epoxides

Published:2023 Issue:14 Volume:47 Page:6551-6562
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Zakrzewska Małgorzata E.¹²,André Paulo J. L.¹,Gomes Clara S. B.¹³⁴^ORCID,Nunes Ana V. M.¹,Rosa Vitor¹^ORCID

Affiliation:

1. LAQV-REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal

2. Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal

3. UCIBIO, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal

4. Associate Laboratory i4HB, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal

Abstract

Three new neutral aryl-BIAN ZnCl2 (where aryl-BIAN = bis(aryl-imino)acenaphthene) complexes were prepared through a green synthesis methodology and employed as catalysts in the cycloaddition reaction of CO2 and epoxides, exhibiting high activity.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D2NJ05621F

Reference69 articles.

1. Global Carbon Budget 2020

2. Carbon dioxide utilization—Electrochemical reduction to fuels and synthesis of polycarbonates

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5. Synthesis of cyclic carbonates from epoxides and CO2

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