Zinc complexes bearing BIAN ligands as efficient catalysts for the formation of cyclic carbonates from CO2 and epoxides

Author:

Zakrzewska Małgorzata E.12,André Paulo J. L.1,Gomes Clara S. B.134ORCID,Nunes Ana V. M.1,Rosa Vitor1ORCID

Affiliation:

1. LAQV-REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal

2. Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal

3. UCIBIO, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal

4. Associate Laboratory i4HB, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal

Abstract

Three new neutral aryl-BIAN ZnCl2 (where aryl-BIAN = bis(aryl-imino)acenaphthene) complexes were prepared through a green synthesis methodology and employed as catalysts in the cycloaddition reaction of CO2 and epoxides, exhibiting high activity.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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