A ratiometric small-molecule fluorescent probe for the selective detection of hypochlorite by an oxidative cyclization reaction: application to commercial disinfectants and live cells

Author:

Banerjee Shilpita1,Banik Dipanjan1,Halder Satyajit2,Karak Anirban1,Ghosh Pintu1,Jana Kuladip2,Mahapatra Ajit Kumar1ORCID

Affiliation:

1. Molecular Sensor and Supramolecular Chemistry Laboratory, Department of Chemistry, Indian Institute of Engineering Science and Technology, Shibpur, Howrah 711 103, India

2. Division of Molecular Medicine, Bose Institute, P 1/12, CIT Scheme VIIM, Kolkata-700 054, India

Abstract

Hypochlorite oxidises the probe TPBN resulting in a ratiometric naked eye color change from yellow to blue. The shifting in emission spectra is a result of weakening of ICT, which is also observed in live-cell imaging study.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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