Metallic cyanoacetylides of copper, silver and gold: generation and structural characterization-Reference-Cited by-同舟云学术

Metallic cyanoacetylides of copper, silver and gold: generation and structural characterization

Published:2016 Issue:41 Volume:18 Page:28538-28547
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Cabezas Carlos¹²³⁴⁵,Barrientos Carmen⁶⁷⁸⁹¹⁰,Largo Antonio⁶⁷⁸⁹¹⁰,Guillemin Jean-Claude¹¹¹²¹³¹⁴¹⁵,Alonso J. L.¹²³⁴⁵

Affiliation:

1. Grupo de Espectroscopia Molecular (GEM)

2. Edificio Quifima

3. Laboratorios de Espectroscopia y Bioespectroscopia

4. Unidad Asociada CSIC

5. Parque Científico Uva

6. Departamento de Química Física y Química Inorgánica

7. Facultad de Ciencias

8. Universidad de Valladolid

9. Campus Miguel Delibes

10. 47011 Valladolid

11. Institut des Sciences Chimiques de Rennes

12. École Nationale Supérieure de Chimie de Rennes

13. CNRS

14. UMR 6226

15. 35708 Rennes Cedex 7

Abstract

Copper, silver and gold cyanoacetylides have been synthesized and characterized in the laboratory using a combination of a laser ablation technique and Fourier transform microwave spectroscopy. A study of the chemical bonding helps to understand the preference for metal–C bonding over metal–N bonding.

Funder

European Research Council

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP04474C

Reference38 articles.

1. The First Precise Molecular Structure of a Monomeric Transition Metal Cyanide, Copper(I) Cyanide

2. Rotational spectroscopy of 3d transition-metal cyanides: Millimeter-wave studies of ZnCN (X 2Σ+)