An ion pair-induced environment-responsive metal–organic gel: en route to smart materials for volatile salt-based nitrogen (VBN) sensing

Author:

Hou Chao-Ping1234ORCID,Leng Ming-Rui12345,Yang Qiong-Yu1234,Xiang Jun-Feng67348,Gong Han-Yuan1234ORCID

Affiliation:

1. College of Chemistry

2. Beijing Normal University

3. Beijing

4. P. R. China

5. Department of Chemistry

6. Institute of Chemistry

7. Chinese Academy of Sciences

8. University of Chinese Academy of Sciences

Abstract

An unusual Ag+–NO3 ion pair-induced metal–organic gel was constructed from the cationic imidazolium ligand 1,4-bis((1-(6-(1H-imidazol-1-yl)pyridin-2-yl)-1H-imidazol-3yl)methyl)benzene (12+) in the mixture of acetonitrile and DMF (1 : 1, v/v).

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Fundamental Research Funds for the Central Universities

Beijing Municipal Commission of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

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