A stereoselective synthesis of (E)- or (Z)-β-arylvinyl halides via a borylative coupling/halodeborylation protocol

Author:

Szyling Jakub12345,Franczyk Adrian1234,Pawluć Piotr5234,Marciniec Bogdan12345,Walkowiak Jędrzej1234ORCID

Affiliation:

1. Centre for Advanced Technologies

2. Adam Mickiewicz University in Poznan

3. 61-614 Poznan

4. Poland

5. Faculty of Chemistry

Abstract

A new highly selective method for the synthesis of (E)-arylvinyl iodides and (E)- or (Z)-β-arylvinyl bromides from easily accessible styrenes and vinyl boronates, on the basis of a one-pot procedure via borylative coupling/halodeborylation is reported.

Funder

Narodowe Centrum Nauki

Narodowe Centrum Badań i Rozwoju

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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