A stereoselective synthesis of (E)- or (Z)-β-arylvinyl halides via a borylative coupling/halodeborylation protocol
Author:
Affiliation:
1. Centre for Advanced Technologies
2. Adam Mickiewicz University in Poznan
3. 61-614 Poznan
4. Poland
5. Faculty of Chemistry
Abstract
A new highly selective method for the synthesis of (E)-arylvinyl iodides and (E)- or (Z)-β-arylvinyl bromides from easily accessible styrenes and vinyl boronates, on the basis of a one-pot procedure via borylative coupling/halodeborylation is reported.
Funder
Narodowe Centrum Nauki
Narodowe Centrum Badań i Rozwoju
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00054E
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3. A General Copper-Catalyzed Coupling of Azoles with Vinyl Bromides
4. Stereo- and Regiospecific Cu-Catalyzed Cross-Coupling Reaction of Vinyl Iodides and Thiols: A Very Mild and General Route for the Synthesis of Vinyl Sulfides
5. Stereoselective Direct Copper-Catalyzed Alkenylation of Oxazoles with Bromoalkenes
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