Ultrastable, cationic three-dimensional lead bromide frameworks that intrinsically emit broadband white-light
Author:
Affiliation:
1. Shanghai Key Laboratory of Chemical Assessment and Sustainability
2. School of Chemical Science and Engineering
3. Tongji University
4. Shanghai 200092
5. P. R. China
Abstract
We have discovered the first two lead halide materials adopting a purely cationic inorganic 3D topology. The highly distorted PbII centers afford strong electron–phonon coupling in a deformable lattice and unusual broadband white-light emission as an intrinsic property.
Funder
National Natural Science Foundation of China
Science and Technology Commission of Shanghai Municipality
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC04118G
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