Hydrogenation of pentenal over supported Pt nanoparticles: influence of Lewis-acid sites in the conversion pathway-Reference-Cited by-同舟云学术

Hydrogenation of pentenal over supported Pt nanoparticles: influence of Lewis-acid sites in the conversion pathway

Published:2021 Issue:40 Volume:45 Page:18881-18887
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Wei Xuejiao¹²,Zhou Yajuan¹,Sun Xiaonan¹,Jiang Fuhua¹,Zhang Jintao¹,Wu Zeying¹,Wang Fei³,Li Gao²^ORCID

Affiliation:

1. School of Chemical Engineering and Materials, Changzhou Institute of Technology, Changzhou 213032, China

2. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

3. Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical and Engineering, Changzhou University, Changzhou 213164, China

Abstract

The superb TOF and high selectivity of Pt/CeAl are associated with the surface properties (e.g. medium Lewis acidic site). The unsaturated Ce4+/Al3+ cations pairs act as the acid sites and electron acceptors to polarize the CO bonds.

Funder

National Natural Science Foundation of China

Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions

Changzhou Science and Technology Bureau

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ03979B

Reference48 articles.

1. Guidelines to Achieving High Selectivity for the Hydrogenation of α,β-Unsaturated Aldehydes with Bimetallic and Dilute Alloy Catalysts: A Review