A synthetic equivalent for unknown 1,3-zwitterions? – A K/OR phosphinidenoid complex with an additional Si

A synthetic equivalent for unknown 1,3-zwitterions? – A K/OR phosphinidenoid complex with an additional Si–Cl function

Published:2020 Issue:27 Volume:56 Page:3899-3902
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kunzmann Robert¹²³⁴^ORCID,Omatsu Yamato⁵⁶⁷⁸,Schnakenburg Gregor¹²³⁴^ORCID,Espinosa Ferao Arturo⁹¹⁰¹¹¹²¹³^ORCID,Yanagisawa Tatsuya⁵⁶⁷⁸^ORCID,Tokitoh Norihiro⁵⁶⁷⁸^ORCID,Streubel Rainer¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische Chemie der Rheinischen Friedrich-Wilhelms-Universität Bonn

2. Gerhard-Domagk-Straße 1

3. 53121 Bonn

4. Germany

5. Institute for Chemical Research

6. Kyoto University

7. Uji

8. Japan

9. Departamento de Química Orgánica

10. Facultad de Química

11. Universidad de Murcia

12. 30100 Murcia

13. Spain

Abstract

Although the chemistry of frustrated Lewis pairs (FLPs) has seen tremendous developments, investigations on anionic, mono-molecular FLPs are still scarce and 1,3-zwitterions are unknown, but a functional K/OR phosphinindenoid complex can be used instead.

Funder

Deutsche Forschungsgemeinschaft

Kyoto University Education and Research Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC00024H

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