Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex
Author:
Affiliation:
1. Institute of Inorganic Chemistry
2. RWTH Aachen University
3. 52056 Aachen
4. Germany
5. Graduate School of Engineering Science
6. Osaka University
7. Osaka
8. Japan
Abstract
Deprotonation of a formato ligand by cis-coordinated carbyne resulted in the formation of a dioxo complex, CO, ethylene and propylene.
Funder
Deutsche Forschungsgemeinschaft
Hans Böckler Stiftung
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03056A
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4. Reactivity Patterns of Carbyne Hydride Complexes of Tungsten
5. Synthesis of a four-coordinate titanium(iv) oxoanion via deprotonation and decarbonylation of complexed formate
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