Atomistic picture of electronic metal support interaction and the role of water-Reference-Cited by-同舟云学术

Atomistic picture of electronic metal support interaction and the role of water

Published:2024 Issue: Volume: Page:
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Fusek Lukáš¹²^ORCID,Farnesi Camellone Matteo³^ORCID,Ronovský Michal²^ORCID,Kastenmeier Maximilian¹^ORCID,Skála Tomáš²^ORCID,Kumar Samal Pankaj²^ORCID,Tsud Nataliya²^ORCID,Mehl Sascha⁴^ORCID,Škvára Jan²,Dolák Tomáš²,Uvarov Vitalii²^ORCID,Setvín Martin²^ORCID,Johánek Viktor²^ORCID,Fabris Stefano³^ORCID,Brummel Olaf¹^ORCID,Libuda Jörg¹^ORCID,Mysliveček Josef²^ORCID,Piccinin Simone³^ORCID,Lykhach Yaroslava¹^ORCID

Affiliation:

1. Interface Research and Catalysis, ECRC, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3, Erlangen 91058, Germany

2. Charles University, Faculty of Mathematics and Physics, Department of Surface and Plasma Science, V Holešovičkách 2, Prague 18000, Czech Republic

3. Istituto Officina dei Materiali, Consiglio Nazionale delle Ricerche (CNR-IOM), Via Bonomea 265, Trieste 34136, Italy

4. Elettra-Sincrotrone Trieste SCpA, Strada Statale 14, km 163.5, Basovizza-Trieste 34149, Italy

Abstract

Electronic metal support interaction in the Pt/Co3O4(111) model catalysts involves cation exchange yielding atomically dispersed Pt2+ and Pt4+ species. In the presence of water, these can be stabilized in the form of triaqua complexes.

Funder

Central European Research Infrastructure Consortium

Grantová Agentura, Univerzita Karlova

Grantová Agentura České Republiky

Deutsche Forschungsgemeinschaft

Ministerstvo Školství, Mládeže a Tělovýchovy

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA06595B

Reference54 articles.

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4. Electronic perturbations

5. A New Type of Strong Metal–Support Interaction and the Production of H2 through the Transformation of Water on Pt/CeO2(111) and Pt/CeOx/TiO2(110) Catalysts