Rhenium and technetium bi- and tricarbonyl complexes in a new strategy for biomolecule incorporation using click chemistry
Author:
Affiliation:
1. Washington State University
2. Pullman, USA
3. University of Missouri
4. Columbia, USA
Abstract
Bi and tri-carbonyl Re/99mTc complexes can be selectively formed by temperature control at macroscopic and radio-chemical concentrations using a combination of Huisgen “clicked” and phosphine ligands.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00684D
Reference27 articles.
1. R. Alberto , in Medicinal Organometallic Chemistry , eds. G. Jaouen and N. Metzler-Nolte , Springer , Berlin, Heidelberg , 2010 , vol. 32 , pp. 219–246
2. A Novel Organometallic Aqua Complex of Technetium for the Labeling of Biomolecules: Synthesis of [99mTc(OH2)3(CO)3]+ from [99mTcO4]- in Aqueous Solution and Its Reaction with a Bifunctional Ligand
3. Basic aqueous chemistry of [M(OH2)3(CO)3]+ (M=Re, Tc) directed towards radiopharmaceutical application
4. Target-specific Tc(CO)3-complexes for in vivo imaging
5. Influence of the Denticity of Ligand Systems on the in Vitro and in Vivo Behavior of 99mTc(I)−Tricarbonyl Complexes: A Hint for the Future Functionalization of Biomolecules
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