Reactant or reagent? Oxidation of H2 at electronically distinct nickel-thiolate sites [Ni2(μ-SR)2]+ and [Ni

Reactant or reagent? Oxidation of H2 at electronically distinct nickel-thiolate sites [Ni2(μ-SR)2]+ and [Ni–SR]+

Published:2018 Issue:31 Volume:47 Page:10561-10568
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Koch Felix¹²³⁴,Berkefeld Andreas¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Eberhard Karls Universität Tübingen

3. 72076 Tübingen

4. Germany

Abstract

The chemical bond between a Lewis-acidic metal and a Brønsted/Lewis-basic sulphur donor provides M–S structures with functional properties that are relevant for a variety of processes such as the heterolytic cleavage of H₂.

Funder

Baden-Württemberg Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00275D

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