A comparison of MOP-phosphonite ligands and their applications in Rh(i)- and Pd(ii)-catalysed asymmetric transformations-Reference-Cited by-同舟云学术

A comparison of MOP-phosphonite ligands and their applications in Rh(i)- and Pd(ii)-catalysed asymmetric transformations

Published:2016 Issue:39 Volume:45 Page:15660-15670
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fleming James T.¹²³⁴⁵,Wills Corinne¹²³⁴⁵,Waddell Paul G.¹²³⁴⁵,Harrington Ross W.¹²³⁴⁵,Higham Lee J.¹²³⁴⁵

Affiliation:

1. School of Chemistry

2. Bedson Building

3. Newcastle University

4. Newcastle upon Tyne

5. UK

Abstract

Six chiral MOP-phosphonites have been synthesised and compared via experimental and computational methods in an effort to quantify their differing structural and electronic profiles.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02390H

Reference67 articles.

1. Phosphorus Ligands in Asymmetric Catalysis, ed. A. Börner, Wiley-VCH, Weinheim, 2008

2. Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis, ed. P. C. J. Kamer and P. W. N. M. Van Leeuwen, John Wiley & Sons, Chichester, 2012

3. Chiral Monophosphines as Ligands for Asymmetric Organometallic Catalysis.

4. Air-Stable Chiral Primary Phosphines: A Gateway to MOP Ligands with Previously Inaccessible Stereoelectronic Profiles

5. MOP-phosphonites: A novel ligand class for asymmetric catalysis

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